Patent · US Expired

Process for manufacturing terephthalic acid by oxidation of paraxylene

US4145560A · kind A · utility

6Cited by
1References
10Claims
0Family size

Assignee

Inventors

Key dates

Filing dateApr 14, 1976
Grant dateMar 20, 1979
Priority date
Expiry dateApr 14, 1996

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC07C51/265
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

Process for manufacturing a benzene carboxylic acid by oxidation of an alkyl substituted benzene, and in particular for manufacturing terephthalic acid by oxidation of paraxylene, in which said benzene carboxylic acid, in solution in an aliphatic monocarboxylic acid, such as acetic acid, is oxidized by means of a gas containing molecular oxygen at a temperature T from 80.degree. to 260.degree. C. under a pressure from 2 to 30 kg/cm.sup.2, in the presence of a transition metal compound, in at least one reactor whose internal wall is maintained during the whole reaction time at a temperature, in .degree.C., from T - 10 to T + 100.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.