Patent · US Expired

Process and intermediates for preparing cephalosporin antibiotics

US4148817A · kind A · utility

6Cited by
8References
3Claims
0Family size

Assignee

Inventor

Key dates

Filing dateMar 25, 1976
Grant dateApr 10, 1979
Priority date
Expiry dateMar 25, 1996

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC07F7/1804
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

The silylated and enamine protected D-3- or 4-hydroxyphenylglycine as the sodium salt of the formula ##STR1## wherein A is methyl or ethyl, are crystalline intermediates useful in a new process for the acylation of heterocyclic-thiomethyl-substituted cephalosporin nuclei, e.g. 7-amino-3-(5-methyl-1,3,4-thiadiazole-2-ylthiomethyl)-3-cephem-4-carboxyli c acid and 7-amino-3-(1-methyl-1H-tetrazole-5-ylthiomethyl)-3-cephem-4-carboxylic acid.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.