Patent · US Expired

Reference electrode

US4166021A · kind A · utility

11Cited by
4References
12Claims
0Family size

Assignee

Inventors

Key dates

Filing dateJan 13, 1978
Grant dateAug 28, 1979
Priority date
Expiry dateJan 13, 1998

Classification

  • Technology area (CPC G)Physics
  • CPC primaryG01N27/301
  • WIPO fieldMeasurement
  • WIPO sectorInstruments

Abstract

An improved electrochemical reference electrode for use in potentiometric determinations of species in solution. The body of the electrode is composed of a material substantially permeable to liquid water whose exterior surface, excepting a comparatively small area, is covered by a membrane through which water may pass only by diffusion and which is also ion impermeable. The small area which is not covered forms an opening through the membrane to the body. The body contains a saturated salt slurry. When the electrode is immersed in an aqueous sample solution, water diffuses through the membrane and is transported in bulk across the body. Upon entry into the slurry, the water dissolves the solid salt in the slurry to produce an electrolyte which in turn flows outward through the small area of the body which is not covered by the membrane, whereby a liquid junction is provided between the electrolyte and the sample solution.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.