Molybdenum and tungsten peroxo complexes useful as oxidation catalysts
US4171313A · kind A · utility
8Cited by
5References
31Claims
0Family size
Assignee
Inventors
Key dates
| Filing date | Oct 14, 1977 |
| Grant date | Oct 16, 1979 |
| Priority date | — |
| Expiry date | Oct 14, 1997 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC07C51/285
- WIPO fieldOrganic fine chemistry
- WIPO sectorChemistry
Abstract
A catalytic system for oxidation of organic compounds including olefins, cyclic ketones and secondary alcohols. Soluble peroxo or solid supported oxo or peroxo complexes of molybdenum or tungsten are used in the presence of hydrogen peroxide to effect the oxidation. The resulting products include lactones, hydroxy acids, ketoacids, hydroxy esters and ketoesters from cyclic ketones; ketones from secondary alcohols and polyols or derivatives thereof from allylic alcohols.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.