Patent · US Expired

Process for producing cellulosic shaped articles

US4173613A · kind A · utility

10Cited by
5References
11Claims
0Family size

Assignee

Inventor

Key dates

Filing dateJul 14, 1977
Grant dateNov 6, 1979
Priority date
Expiry dateJul 14, 1997

Classification

  • Technology area (CPC D)Textiles; Paper
  • CPC primaryD01F2/00
  • WIPO fieldMacromolecular chemistry, polymers
  • WIPO sectorChemistry

Abstract

A process for producing shaped articles of cellulose is disclosed, wherein a solution of cellulose in dimethylsulphoxide (DMS0) and formaldehyde, at a formaldehyde/cellulose weight ratio of 0.2 to 2, and at a cellulose concentration of at least 6% by weight based on the volume of DMSO, is spun into a coagulant bath. The coagulant bath contains water, DMSO and ammonia or an ammonium salt, with the DMSO present in an amount of about 25 to 60 weight percent of the mixture of DMSO and water. The ammonia or ammonium salt is present in an amount, calculated as ammonia, of at least 1 gram per liter in the mixture of DMSO and water. The use of the coagulant bath of the present invention permits the cellulosic solution to be formed into shaped articles, and especially into filaments which are useful in the textile field. Other shaped articles which can be made from the cellulosic solution include fibers, threads, membranes, films, and sheets.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.