Chlorine and iron oxide from ferric chloride--process and apparatus
US4174381A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Apr 24, 1978 |
| Grant date | Nov 13, 1979 |
| Priority date | — |
| Expiry date | Apr 24, 1998 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC01G49/06
- WIPO fieldMaterials, metallurgy
- WIPO sectorChemistry
Abstract
An improved industrial process and apparatus are provided for producing chlorine and iron oxide in a multi-stage recirculating-fluidized-bed reactor wherein ferric chloride in the vapor phase is reacted with an excess of oxygen at temperatures from 550.degree. to 800.degree. C. The improvement comprises utilizing a reactor that includes an initial "dense" zone and a downstream "dilute" zone. In the dense zone, a fuel is burned, reactants and recirculated iron oxide particles are heated, ferric chloride is vaporized and at least 50% of the ferric chloride is converted to chlorine and iron oxide. A solids volume fraction from 0.3 to 0.6 and a superficial gas velocity from 0.15 to 0.6 meters/second are maintained in the dense zone. In the downstream dilute zone, a solids fraction from 0.005 to 0.05 is maintained, along with a superficial gas velocity from 1.5 to 6 meters/second which is from 5 to 25 times the superficial gas velocity in the dense zone, and the conversion of ferric chloride is continued to greater than 95% completion.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.