Patent · US Expired

Particle gamma ferric oxide

US4176172A · kind A · utility

16Cited by
3References
1Claims
0Family size

Assignee

Inventors

Key dates

Filing dateNov 28, 1977
Grant dateNov 27, 1979
Priority date
Expiry dateNov 28, 1997

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC01P2006/42
  • WIPO fieldAudio-visual technology
  • WIPO sectorElectrical engineering

Abstract

Synthetic lepidocrocite (gamma ferric oxide monohydrate) having very fine-grained, needle-like crystalline particles, with at least about 70% of the particles having a length to width ratio of greater than 10:1, and a length of up to about 2 microns is made by first oxidizing a vigorously agitated alkaline-treated ferrous chloride solution until the pH is about 2.9-4.1 to form a synthetic lepidocrocite collodial seed slurry. The oxidation of the colloidal seed slurry is continued (optionally in the presence of metallic iron) at a temperature about 80.degree.-140.degree. F. and pH about 2.9-4.1 in the presence of excess ferrous chloride, until from about 1.2 to 5 parts by weight of total product is formed per part by weight of seed. A synthetic magnetic gamma ferric oxide may be made from the synthetic lepidocrocite by optionally coating the lepidocrocite particles with an organic surfactant, reducing, oxidizing and mechanically densifying the gamma ferric oxide particles. Magnetic impulse record members comprising a binding medium having therein the synthetic magnetic gamma ferric oxide are also disclosed.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.