Preparation of lithium amide
US4206191A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Dec 18, 1978 |
| Grant date | Jun 3, 1980 |
| Priority date | — |
| Expiry date | Dec 18, 1998 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02E60/36
- WIPO fieldMaterials, metallurgy
- WIPO sectorChemistry
Abstract
A low temperature method of preparing finely divided lithium amide. A mixture is first formed of bulk pieces of lithium metal with a catalyst such as active metallic cobalt in an inert liquid aromatic hydrocarbon, such as toluene, at about 0.degree. C. to about -60.degree. C. Anhydrous liquid ammonia is then added, aided by stirring, the lithium metal dissolving, two immiscible phases forming, one a so-called lithium-ammonia bronze solution being the top phase, and the toluene being the bottom phase. The formation of the lithium amide is then effected by raising the temperature under conditions of stirring, hydrogen and excess ammonia being liberated and the lithium amide, generally light grey in color, is formed which separates out in a very finely divided solid state, as a slurry in the toluene, and is recovered.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.