Patent · US Expired

Process for the synthesis of urea

US4208347A · kind A · utility

13Cited by
8References
15Claims
0Family size

Assignee

Inventor

Key dates

Filing dateMay 1, 1978
Grant dateJun 17, 1980
Priority date
Expiry dateMay 1, 1998

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY02P20/141
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

An improved isobaric double-recycle process is disclosed for synthesizing urea with the formation of ammonium carbamate as an intermediate, comprising effecting reaction between ammonia and carbon dioxide at high NH.sub.3 :CO.sub.2 molar ratios, a heat-treatment of the synthesis product at substantially the same pressure as that of the synthesis step and in the presence of a stripping gas, and two distinct isobaric recycles of the residual substances and of the substances in excess released from said synthesis product, said process being characterized in that: PA1 (a) said heat-treatment of the synthesis product is carried out in two consecutive stages which are isobaric or substantially isobaric with respect to the synthesis step, in the first of which stages said synthesis product is heated, whereby substantially all the residual ammonium carbamate is decomposed and the decomposition products are displaced together with part of the excess NH.sub.3, while in the second stage the remaining part of the NH.sub.3 excess is displaced by supplying supplemental heat and by injecting thereto a CO.sub.2 stream; and PA1 (b) the gas phase stripped in the first stage is immediately recycled t…

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