Patent · US Expired

Metal salt/amine complexes

US4218377A · kind A · utility

13Cited by
6References
6Claims
0Family size

Assignee

Inventors

Key dates

Filing dateOct 31, 1978
Grant dateAug 19, 1980
Priority date
Expiry dateOct 31, 1998

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC08G65/33396
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

Novel carboxylic acid metal salt/amine complexes of the formula EQU (A.sup..crclbar.).sub.2 Me.sup.2+ .multidot.NH.sub.2 --R.sub.1 --NH.sub.2 in which A is the anion of cyanoacetic acid, pyrrolidonecarboxylic acid, maleimidylcarboxylic acid, succinylimidylcarboxylic acid, benzenesulphonic acid or toluenesulphonic acid or of a methanephosphonic acid monoester or benzenephosphonic acid monoester, Me.sup.2+ is a divalent metal cation and R.sub.1 is a long-chain polyoxyalkylene radical, are obtained by reacting 1 mol of a carboxylic acid metal salt of the formula EQU (A.sup..crclbar.).sub.2 Me.sup.2+ with 1 mol of a diamine of the formula EQU H.sub.2 N--R.sub.1 --NH.sub.2 in a polar organic solvent and in the temperature range of 25.degree. to 200.degree. C. to give the complex compounds of the formula. The novel complex compounds are valuable curing agents for epoxide resins and in mixtures with epoxide resins have an advantageous storage stability.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.