Patent · US Expired

Process for polymerizing olefin

US4226964A · kind A · utility

13Cited by
1References
17Claims
0Family size

Assignee

Inventors

Key dates

Filing dateJan 25, 1979
Grant dateOct 7, 1980
Priority date
Expiry dateJan 25, 1999

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC08F10/00
  • WIPO fieldMacromolecular chemistry, polymers
  • WIPO sectorChemistry

Abstract

In a process for polymerizing an olefin in the presence of a catalyst system combining an organoaluminum compound with a hydrocarbon insoluble solid catalytic component prepared by treating a hydrocarbon solution containing a magnesium compound, a titanium compound and a zirconium compound with an aluminum halide having the formula EQU AlR.sup.1 X.sub.2.sup.1 (R.sup.1 represents an alkyl, aryl or cycloalkyl group and X.sup.1 represents a halogen atom), an improvement characterized in that the magnesium compound is a compound having the formula EQU Mg(OR.sup.2).sub.l X.sub.2-l.sup.2 (R.sup.2 represents an alkyl, aryl or cycloalkyl group; X.sup.2 represents a halogen atom; and l is 1 or 2) and the titanium compound is a compound having the formula EQU Ti(OR.sup.3).sub.n X.sub.4-n.sup.3 (R.sup.3 represents an alkyl, aryl or cycloalkyl group; X.sup.3 represents a halogen atom; n is 1, 2 or 3) and the zirconium compound is a compound having the formula EQU Zr(OR.sup.4).sub.m X.sub.4-m.sup.4 (R.sup.4 represents an alkyl, aryl or cycloalkyl group; X.sup.4 represents a halogen atom; m is 1, 2 or 3) or an alcohol solution of a compound having the formula EQU ZrX.sub.4.sup.4 (X.sup.4 is defi…

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.