Method for producing crosslinked polyethylenes
US4228255A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Jun 28, 1979 |
| Grant date | Oct 14, 1980 |
| Priority date | — |
| Expiry date | Jun 28, 1999 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC08F255/02
- WIPO fieldMacromolecular chemistry, polymers
- WIPO sectorChemistry
Abstract
A novel method for crosslinking a polyolefin comprising reacting a polyolefin, which is a low density polyethylene having a density less than 0.93 and melt index of 0.1-0.5 g/10 min. or a polyolefin mixture containing a low density polyethylene having a density less than 0.93 as major component, with an organic silane and a free radical generating compound to form a silane-grafted polyolefin, then mixing silane-grafted polyolefin with a silanol condensation catalyst, and heating them. According to this method, the crosslinking takes place concurrently with forming by extrusion, and a shaped article having a high degree of crosslinking with smooth surface is obtained. The method according to this invention is especially suited for covering electrical wires with polyolefin.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.