Patent · US Expired

Catalyst demetallization with a reductive SO.sub.2 wash

US4243550A · kind A · utility

12Cited by
8References
24Claims
0Family size

Assignee

Inventors

Key dates

Filing dateJun 14, 1976
Grant dateJan 6, 1981
Priority date
Expiry dateJun 14, 1996

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY10S502/516
  • WIPO fieldChemical engineering
  • WIPO sectorChemistry

Abstract

A process for the removal of metal poisons such as nickel, iron and/or vanadium from a hydrocarbon conversion catalyst which includes the step of contacting the catalyst with a reductive wash medium comprising an aqueous, preferably saturated, solution of SO.sub.2 to remove at least a portion of the metal poisons. The vanadium and nickel metals may be recovered from the resultant used wash solution for possible metallurgical use. The SO.sub.2 reductively washed catalyst may also be subjected to a subsequent oxidative wash such as hydrogen peroxide wash prior to its return to the hydrocarbon conversion process.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.