Patent · US Expired

Process for recovering arsenic compounds by sodium hydroxide leaching

US4244927A · kind A · utility

14Cited by
3References
19Claims
0Family size

Assignee

Inventors

Key dates

Filing dateJul 27, 1979
Grant dateJan 13, 1981
Priority date
Expiry dateJul 27, 1999

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY02P10/20
  • WIPO fieldMaterials, metallurgy
  • WIPO sectorChemistry

Abstract

An arsenic-recovery process primarily for use in conjunction with the hydrometallurgical processing of arsenic-containing materials for metal recovery. Arsenic is recovered from ferric arsenate by reaction with sodium hydroxide in accordance with the following general reaction: EQU 3NaOH+FeAsO.sub.4 .fwdarw.Na.sub.3 AsO.sub.4 +Fe(OH).sub.3 During the processing of high arsenic materials such as smelter flue dust, extremely insoluble ferric-arsenic compounds are generated to immobilize the arsenic during leaching of the metals. The arsenic may be recovered in saleable form from the arsenic-containing residues by leaching with sodium hydroxide and crystallizing the arsenic salts from the leach residue.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.