Patent · US Expired

Electrolysis of alkali metal chloride in a cell having a nickel-molybdenum cathode

US4248679A · kind A · utility

17Cited by
5References
3Claims
0Family size

Assignee

Inventors

Key dates

Filing dateJan 24, 1979
Grant dateFeb 3, 1981
Priority date
Expiry dateJan 24, 1999

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC25B11/091
  • WIPO fieldSurface technology, coating
  • WIPO sectorChemistry

Abstract

Disclosed herein is a cathode having an electroconductive substrate and a porous surface. The porous surface is characterized by containing a major portion of nickel and a hydrogen overvoltage reducing amount of molybdenum. The molybdenum may be present as elemental molybdenum, as an alloy with nickel, or as a molybdenum compound. Also disclosed is an electrolytic cell having an anode, a cathode, and a separator between the anode and cathode, where the cathode is characterized by a porous surface having a major portion of nickel and a hydrogen over voltage reducing amount of molybdenum, which molybdenum may be present as elemental molybdenum, and molybdenum alloy with nickel or a molybdenum compound. Further disclosed is a method of electrolyzing an alkali metal chloride brine by passing an electrical current from an anode to a cathode to evolve chlorine at the anode and hydroxyl ion at the cathode. The cathode is characterized by a porous surface containing a major portion of nickel and hydrogen overvoltage reducing amount of molybdenum. Also disclosed is a method of preparing a porous nickel electrode by flame spraying nickel bearing particles, leachable constituent bearing parti…

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.