Acrylonitrile polymerization in fluorinated hydrocarbons
US4255546A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Sep 20, 1979 |
| Grant date | Mar 10, 1981 |
| Priority date | — |
| Expiry date | Sep 20, 1999 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC08F2/06
- WIPO fieldMacromolecular chemistry, polymers
- WIPO sectorChemistry
Abstract
The invention relates to a process for the production of polyacrylonitrile or acrylonitrile copolymers, the polymerization being carried out at a temperature of from -40.degree. to +60.degree. C. optionally under pressure in an aliphatic chlorofluorine or fluorine substituted hydrocarbon containing up to 8 carbon atoms and having a boiling point of from -60.degree. to +50.degree. C. or in mixtures thereof having boiling ranges of from -60.degree. to +50.degree. C. and using a starter system comprising a hydroperoxide sulphur dioxide and an acid. The system may also contain aliphatic hydrocarbons in such quantities that a non-inflammable mixture is formed.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.