Carbonylation process
US4255591A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Nov 20, 1978 |
| Grant date | Mar 10, 1981 |
| Priority date | — |
| Expiry date | Nov 20, 1998 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC07C51/12
- WIPO fieldOrganic fine chemistry
- WIPO sectorChemistry
Abstract
There is provided an improved continuous homogeneous catalytic carbonylation process wherein a mixed gas stream is removed from the carbonylation reactor, condensable liquids separated from said gas stream and said gas stream vented, the improvement comprising contacting said gas stream with a plurality of hollow fiber membranes selectively permeable to hydrogen under conditions substantially non-degrading of the membranes to generate a non-permeated gas stream of higher carbon monoxide content and recycling said non-permeated gas stream to the carbonylation process reactor. There is also provided for the recovery and recycle to the process of carbonylation products such as acetic or propionic acids by adsorption and removal from a solid adsorbent or absorption in a liquid absorbent.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.