Patent · US Expired

Production of fructose and useful by-products

US4263052A · kind A · utility

14Cited by
45References
12Claims
0Family size

Assignee

Inventors

Key dates

Filing dateOct 12, 1979
Grant dateApr 21, 1981
Priority date
Expiry dateOct 12, 1999

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY10S426/807
  • WIPO fieldFood chemistry
  • WIPO sectorChemistry

Abstract

A process for obtaining fructose solutions or solid fructose, a raw material containing sucrose and/or similar fructofuranosides is hydrolyzed to fructose and glucose and treated with a calcium base (e.g. calcium oxide or hydroxide) to precipitate calcium-sugar complexes. The precipitate is slurried in water and then treated with phosphoric acid to liberate (e.g. at a pH of 5.5 to 9) a fructose solution of high purity (i.e. de-complex the calcium-fructose complex), with precipitation of useful calcium phosphate salts. Phosphoric acid has been found to have significant advantages over carbonic acid or carbon dioxide as the fructose-liberating (de-complexing) agent, e.g. better yields and more useful by-products. Solid fructose can be obtained from the fructose solution in a known manner. The filtrate from the calcium-sugar complexing step can be acidified to yield stable, useful, fructose-depleted by-products.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.