Recovery of polymeric cation exchange materials for reuse by converting by reaction to the precursor form
US4266036A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Oct 23, 1979 |
| Grant date | May 5, 1981 |
| Priority date | — |
| Expiry date | Oct 23, 1999 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02W30/62
- WIPO fieldOther special machines
- WIPO sectorMechanical engineering
Abstract
Normally solid copolymers of a fluorinated vinyl monomer and a perfluorinated vinyl compound having a carboxyl and/or sulfonyl group attached directly to the perfluorinated vinyl group or indirectly through an alkyl or ether linkage have been found to be soluble in low molecular weight polymers of perhalogenated alkyl ethers, low molecular weight polymers of perhalogenated alkyls and perfluoro kerosenes, each of said solvent materials having boiling points between about 200.degree. C. and 350.degree. C. The copolymeric material dissolved in accordance with the instant invention can readily be resolidified by solvent removal and hydrolyzed or converted to the salt form to become a cation exchange material having an equivalent weight in the range of 1000 to 1600. When these cation exchange materials in the salt form become damaged or contaminated during operation, for example in an electrochemical cell, they may now be reclaimed rather than discarded. The process involves conversion of the salt form of the cation exchanger to the precursor sulfonyl fluoride, carbonyl fluoride, sulfonate ester, or carboxylate ester form followed by dissolution in one of the solvents mentioned above. D…
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.