Manufacture of homopolymers and copolymers of .alpha.-monoolefins
US4282341A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Sep 12, 1979 |
| Grant date | Aug 4, 1981 |
| Priority date | — |
| Expiry date | Sep 12, 1999 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC08F10/00
- WIPO fieldMacromolecular chemistry, polymers
- WIPO sectorChemistry
Abstract
A process for the manufacture of homopolymers and copolymers of .alpha.-monoolefins by polymerizing the monomer or monomers at relatively low temperatures under relatively low pressures by means of a Ziegler-Natta catalyst comprising (I) a titanium chloride component and (II) an aluminumalkyl component, wherein the titanium chloride component (I) employed is obtained by exposing a conventional catalyst component consisting, or substantially consisting, of titanium trichloride or titanium tetrachloride, to a carbon dioxide atmosphere under specific conditions. Catalysts obtained from titanium chloride components (I) which have been treated in this way exhibit a relatively long induction period.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.