Low residual monomer .alpha.-methylstyrene-acrylonitrile copolymers and ABS blends therefrom
US4294946A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Jul 21, 1980 |
| Grant date | Oct 13, 1981 |
| Priority date | — |
| Expiry date | Jul 21, 2000 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC08F257/02
- WIPO fieldMacromolecular chemistry, polymers
- WIPO sectorChemistry
Abstract
A process for preparing a thermoplastic resin having high heat resistance by emulsion polymerization of an .alpha.-alkylstyrene compound of the formula: ##STR1## wherein R.sub.1 is C.sub.1 -C.sub.3 alkyl and R.sub.2 is hydrogen, C.sub.1 -C.sub.3 alkyl or halo(C.sub.1 -C.sub.3)alkyl and an unsaturated nitrile in a weight proportion of 65:35 to 80:20 in the presence of a radical initiator, characterized in that the whole amount of the .alpha.-alkylstyrene compound and 10 to 99% by weight of the unsaturated nitrile on the basis of its total amount are first subjected to polymerization and, after the polymerization, the remaining portion of the unsaturated nitrile is added to the reaction mixture and the resultant mixture is subjected to further polymerization until the polymerization is substantially completed.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.