Process for demetallation and desulfurization of heavy hydrocarbons
US4297242A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Jul 14, 1980 |
| Grant date | Oct 27, 1981 |
| Priority date | — |
| Expiry date | Jul 14, 2000 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC10G2300/107
- WIPO fieldChemical engineering
- WIPO sectorChemistry
Abstract
Disclosed is a two-stage catalytic process for hydrodemetallation and hydrodesulfurization of heavy hydrocarbon streams containing asphaltenes and a substantial amount of metals. The first stage of this process comprises contacting the feedstock in a first reaction zone with hydrogen and a demetallation catalyst comprising hydrogenation metal selected from Group VIB and/or Group VIII deposed on a large-pore, high surface area inorganic oxide support; the second stage of the process comprises contacting the effluent from the first reaction zone with a catalyst consisting essentially of hydrogenation metal selected from Group VIB deposed on a smaller-pore, catalytically active support comprising alumina, said second-stage catalyst having a surface area within the range of about 150 m.sup.2 /gm to about 300 m.sup.2 /gm, having a majority of its pore volume in pore diameters within the range of about 80 A to about 130 A, and the catalyst has a pore volume within the range of about 0.4 cc/gm to about 0.9 cc/gm.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.