Patent · US Expired

Process of making phenylacrylic esters

US4309350A · kind A · utility

6Cited by
3References
10Claims
0Family size

Assignee

Inventors

Key dates

Filing dateJan 24, 1980
Grant dateJan 5, 1982
Priority date
Expiry dateJan 24, 2000

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC07D317/60
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

The (+), (-) and (.+-.) forms of the compounds of formula I ##STR1## wherein R.sup.1 is hydrogen or a methoxy, ethoxy, propoxy, methylthio, ethylthio, propylthio, fluoro, chloro, bromo, methyl, ethyl, nitro or amino group, and PA0 R.sup.2 is a hydrogen or methyl group or R.sup.1 and R.sup.2 together form a methylenedioxy group; PA0 R.sup.3 is hydrogen, or a lower alkyl group, or one of the following groups (a) to (d): PA1 (a) m-phenoxybenzyl, PA1 (b) 2-benzyl-4-furylmethyl PA1 (c) .alpha.-cyano-m-phenoxybenzyl PA1 (d) 3-4-methylenedioxy-benzyl, PA0 and R.sup.4 and R.sup.5 are the same or different groups and each is a fluoro, bromo, chloro or methyl group. The compounds of formula I in which R.sup.3 is one of groups (a) to (d) are extremely active as insecticides (except when R.sup.1 is an amino group). The compounds also possess the property of contact repellency to insects.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.