Patent · US Expired

Spheroidal alumina particulates having bifold porosity and process for their preparation

US4315839A · kind A · utility

22Cited by
2References
36Claims
0Family size

Assignee

Inventors

Key dates

Filing dateFeb 26, 1980
Grant dateFeb 16, 1982
Priority date
Expiry dateFeb 26, 2000

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY10S502/503
  • WIPO fieldChemical engineering
  • WIPO sectorChemistry

Abstract

Spheroidal alumina particulates having bifold porosity are prepared by (i) intimately admixing, at a pH of less than about 7.5, (a) a sol of a member selected from the group consisting of ultrafine boehmite and pseudo-boehmite, said sol being devoid of amorphous alumina and the concentration by weight thereof, in content by weight of Al.sub.2 O.sub.3, being between 5 and 25%, with (b) from 30 to 95% by weight, based upon the total solids content of the admixture, of spheroidal alumina particulates essentially completely in at least one of the phases eta, gamma, delta and theta, such particulates having a micropore volume ranging from about 0.4 to 1 cm.sup.3 /g, a specific surface ranging from about 100 to 350 m.sup.2 /g, and particle diameters ranging from about 1 to 50 microns; (ii) prilling said intimate admixture into spheroidal particulates and gelling the same; and then, (iii) recovering, drying and calcining said gelled particulates at a temperature of from 550.degree. to 1100.degree. C. The resultant particulates having bifold porosity are useful as catalysts or catalyst supports.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.