Patent · US Expired

Method for electrolyzing alkali metal halide

US4316781A · kind A · utility

4Cited by
2References
5Claims
0Family size

Assignee

Inventors

Key dates

Filing dateSep 30, 1980
Grant dateFeb 23, 1982
Priority date
Expiry dateSep 30, 2000

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC25B1/46
  • WIPO fieldSurface technology, coating
  • WIPO sectorChemistry

Abstract

An improved method for electrolyzing alkali metal halide. Electrolysis is carried out by supplying an aqueous solution of a halide of alkali metal into an anode chamber partitioned by a cation-exchange membrane and water into a cathode chamber to obtain halogen from the anode chamber and hydrogen and alkali hydroxide from the cathode chamber. The cation-exchange membrane is a fluorocarbon polymer membrane which is prepared by arranging one side thereof to have a cation exchange group concentration lower by 10 to 30% within a depth range of 1 to 100.mu. than that of the other side. The anode chamber is prepared with this side of the membrane which has the lower cation exchange group concentration arranged to face the anode chamber. By this arrangement, a high purity alkali hydroxide can be manufactured at a high rate of decomposition of halide of alkali metal and at a high current efficiency.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.