Patent · US Expired

Method of manufacturing hydrogen peroxide

US4336240A · kind A · utility

37Cited by
1References
10Claims
0Family size

Assignee

Inventors

Key dates

Filing dateApr 22, 1981
Grant dateJun 22, 1982
Priority date
Expiry dateApr 22, 2001

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC01B15/029
  • WIPO fieldMaterials, metallurgy
  • WIPO sectorChemistry

Abstract

A process for producing hydrogen peroxide wherein a gaseous mixture comprising hydrogen and oxygen is contacted with a catalyst in the presence of water and an organic solvent wherein: PA1 (i) the organic solvent is immiscible with water and unreactive with hydrogen peroxide under the contacting conditions; PA1 (ii) the distribution coefficient for hydrogen peroxide between the water and the organic solvent is greater than 1; PA1 (iii) the catalyst is of the formula L.sub.2 MX.sub.2 wherein L is a ligand represented by the formula A R.sub.1 R.sub.2 R.sub.3 wherein R.sub.1 R.sub.2 and R.sub.3 are alkyl, cycloalkyl or aryl groups, hydrogen or halogen, A is a Group 5b element selected from the group consisting of nitrogen, phosphorous and arsenic, M is a Group 8 metal and X is halogen, said catalyst being soluble in said organic solvent and insoluble in water; and PA1 (iv) the gaseous mixture is non-ignitable under the process conditions characterized in that the organic solvent is selected from the group consisting of fluorocarbons, halofluorocarbons and mixtures thereof.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.