Patent · US Expired

Hydrogen regeneration of coke-selectivated crystalline aluminosilicate catalyst

US4358395A · kind A · utility

29Cited by
3References
9Claims
0Family size

Assignee

Inventors

Key dates

Filing dateSep 11, 1978
Grant dateNov 9, 1982
Priority date
Expiry dateSep 11, 1998

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY02P20/584
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

A method is provided for regeneration of a catalyst comprising a crystalline aluminosilicate zeolite characterized by a silica to alumina mole ratio of at least about 12, a constraint index, as hereinafter defined, within the approximate range of 1 to 12, which catalyst has undergone controlled precoking by exposing the same to a thermally decomposable organic compound at a temperature in excess of the decomposition temperature of said compound but less than about 1200.degree. F., at a hydrogen to organic compound mole ratio of between 0 and 1 to deposit at least about 1 weight percent coke thereon, such precoked catalyst having been deactivated by formation of a carbonaceous deposit thereon as a result of use of the same in catalytically converting an organic charge under conditions less severe, i.e., at a lower temperature and/or a higher hydrogen concentration than those employed during said precoking which comprises contacting the aged catalyst with an atmosphere comprising hydrogen at a temperature between about 800.degree. F. and about 1200.degree. F. and a pressure between about 0 and about 2000 psig for a period of time sufficient to at least partially restore the activity …

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.