Patent · US Expired

Process for catalytically converting methanol to formaldehyde

US4358623A · kind A · utility

18Cited by
7References
6Claims
0Family size

Assignee

Inventors

Key dates

Filing dateJul 23, 1981
Grant dateNov 9, 1982
Priority date
Expiry dateJul 23, 2001

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC07C45/38
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

In catalytically oxidizing methanol in the vapor phase according to already-known processes for the production of formaldehyde, the hot formaldehyde-containing gaseous effluent of the catalytic converter is rapidly cooled by being passed through the tubes of a heat exchanger which are filled with balls composed of a solid which is substantially inert toward formaldehyde. As compared with a similar cooling system in which the tubes are empty or in which enhancement of heat transfer is attempted by using metal heat-transfer enhancement devices such as twisted metal ribbons, the present method affords reduced post-reaction decomposition of formaldehyde while at the same time allowing use of a relatively high temperature on the shell side of the heat exchanger whereby it becomes possible to raise steam at a pressure higher than that characteristic of the prior art.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.