Vanadium-hydrogen-phosphorus-oxygen catalytic material
US4374756A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Sep 9, 1981 |
| Grant date | Feb 22, 1983 |
| Priority date | — |
| Expiry date | Sep 9, 2001 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC07C51/215
- WIPO fieldOrganic fine chemistry
- WIPO sectorChemistry
Abstract
Catalytic material is provided by a composition comprising the elements vanadium, non-water-contained hydrogen, phosphorus and non-water-contained oxygen. The VHPO elements are present in a relatively fixed atomic ratio range, there being more non-water-contained oxygen present than phosphorus by an atomic ratio of greater than five to one. The catalytic material comprises an anhydrous primary component having vanadium of mixed valence, hydrogen, phosphorus and oxygen in an empirical relationship defined by VH.sub.x PO.sub.y, wherein "x" has an average value in a range from about 1.29 to about 1.40, and "y" has an average value in a range from about 5.46 to about 5.55. The anhydrous VHPO catalytic material may also be described by a structural formula (VO).sub.m (VO.sub.2).sub.n H.sub.2n (PO.sub.4).sub.n (P.sub.2 O.sub.7).sub.m/2, wherein m+n=3, "m" has an average value in a range from about 0.90 to about 1.07, and "n" has an average value in a range from about 1.93 to about 2.10. The primary component is mostly amorphous and in its substantially anhydrous form is characterized by a powder X-ray diffraction pattern having broad peaks with CuK.alpha. d-spacings of 4.30, 4.17 and 3.0…
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.