Patent · US Expired

Metal sulphide extraction

US4378275A · kind A · utility

36Cited by
7References
31Claims
0Family size

Assignee

Inventors

Key dates

Filing dateDec 3, 1981
Grant dateMar 29, 1983
Priority date
Expiry dateDec 3, 2001

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY02P10/20
  • WIPO fieldMaterials, metallurgy
  • WIPO sectorChemistry

Abstract

A process is described for recovering non-ferrous metal values from a metal-containing sulphide material containing at least one non-ferrous metal selected from zinc, copper, lead, cobalt, nickel, silver and gold, as well as iron, comprising leaching the complex sulphide material under oxidizing conditions in a leach stage with an acidic aqueous chloride lixiviant solution containing magnesium chloride, thereby to solubilize non-ferrous metal values in the material and to leave a residue comprising iron in oxide or hydrated oxide form and also sulphur, passing resulting non-ferrous metal-containing leach liquor to a metal recovery section including a solvent extraction stage in which non-ferrous metal values are recovered by liquid-liquid extraction using a hydrophobic organic extractant phase containing a cationic transport agent for non-ferrous metal transport, recovering from the solvent extraction stage an aqueous magnesium chloride-containing raffinate, subjecting a portion of the aqueous magnesium chloride-containing raffinate from the solvent extraction stage to high temperature hydrolysis, thereby liberating hydrogen chloride and magnesium oxide, recycling another portion o…

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.