Patent · US Expired

Process for the purification of terephthalic acid

US4380662A · kind A · utility

20Cited by
3References
11Claims
0Family size

Assignee

Inventors

Key dates

Filing dateMar 16, 1981
Grant dateApr 19, 1983
Priority date
Expiry dateMar 16, 2001

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC07C51/48
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

Disclosed is a process for the purification of a crude terephthalic acid product contaminated with up to 10% by weight of partially oxidized impurities including p-toluic acid and 4-carboxybenzaldehyde, comprising the steps of dissolving the crude product in water by heating up to a temperature at least about 5.degree. C. higher than necessary for having the resulting solution saturated with terephthalic acid; cooling the resulting solution down to a temperature not lower than about 185.degree. C. to precipitate purified crystals; recovering the purified crystals by solid-liquid separation at a temperature not lower than that used for the precipitation of the purified crystals; and washing the recovered crystals by contacting with water at a temperature which is at least as high as the temperature of the recovery step.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.