Process for extracting tungsten and molybdenum values from solution
US4383980A · kind A · utility
Assignee
Inventor
Key dates
| Filing date | Dec 9, 1980 |
| Grant date | May 17, 1983 |
| Priority date | — |
| Expiry date | Dec 9, 2000 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY10S423/14
- WIPO fieldMaterials, metallurgy
- WIPO sectorChemistry
Abstract
The instant invention relates to a process for removing tungsten, and/or molybdenum generally, as the tungstate and/or the molybdate anion, from aqueous solutions, e.g. brines by contacting such solutions with a high-surface area oxide selected from the group consisting of manganese and iron oxides, preferably manganese or iron hydrous oxide, whereby tungsten or molybdenum is adsorbed on said high-surface area oxide. The instant process provides selectivity for tungsten as well as molybdenum even though they are present in solutions containing various other materials such as sodium, potassium, calcium, etc. ions. This process is preferably applicable to removal of tungsten from high pH brines such as a brine having a pH of at least 9, for example greater than 10. The oxide adsorbent may be regenerated by contacting with an aqueous solution having a pH higher than the brine from which the tungsten and/or the molybdenum has been removed.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.