Patent · US Expired

Concentrated sulphuric acid treatment of an alkylphenyl acid phosphate extractant

US4385037A · kind A · utility

2Cited by
8References
25Claims
0Family size

Assignee

Inventors

Key dates

Filing dateMay 16, 1980
Grant dateMay 24, 1983
Priority date
Expiry dateMay 16, 2000

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY02P10/20
  • WIPO fieldMaterials, metallurgy
  • WIPO sectorChemistry

Abstract

Uranium in wet-process phosphoric acid in the tetravalent state is extracted with an alkylphenyl acid phosphate extractant comprising a mixture of mono- and di(alkylphenyl) esters of orthophosphoric acid. The pregnant extractant is stripped with a suitable stripping solution, and the barren extractant recycled to the extractant step. At least a portion of the recycled extractant is treated with concentrated sulphuric acid to remove organic and inorganic impurities including alkylphenol present in the barren extractant as a result of hydrolysis from the mixture of mono- and di-(alkylphenyl) esters of orthophosphoric acid to regenerate the extractant.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.