Patent · US Expired

Recovery of rhodium and cobalt low pressure oxo catalyst

US4390473A · kind A · utility

13Cited by
7References
7Claims
0Family size

Assignee

Inventor

Key dates

Filing dateJun 21, 1982
Grant dateJun 28, 1983
Priority date
Expiry dateJun 21, 2002

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY02P20/584
  • WIPO fieldChemical engineering
  • WIPO sectorChemistry

Abstract

Disclosed is a process for recovering rhodium and cobalt from a low pressure oxo catalyst solution containing ligandized (modified) rhodium and cobalt, organic solvent, and at least trace amounts of oxo aldehyde, which comprises contacting the catalyst solution with an oxygen containing gas and aqueous formic acid to form an organic phase and an aqueous phase, wherein the aqueous phase contains rhodium formate and cobalt formate solublized therein, and thereafter separating said phases to isolate said formates from the organic solvent, by-products and the like, for recycle to the reactor or for further treatment for use in the same or different processes.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.