Patent · US Expired

Method of treating electrolytic solution of copper for purification and reuse thereof

US4404071A · kind A · utility

4Cited by
3References
11Claims
0Family size

Assignee

Inventors

Key dates

Filing dateApr 26, 1982
Grant dateSep 13, 1983
Priority date
Expiry dateApr 26, 2002

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY02P10/20
  • WIPO fieldSurface technology, coating
  • WIPO sectorChemistry

Abstract

There is disclosed an improved method of treating a spent electrolyte of copper from a cell for electrolytic refining of copper for the purpose of purification and reuse of the spent electrolyte. The process comprises the steps of: pretreating the spent electrolyte for removing copper therefrom until the copper content is greatly reduced but still remains at a level which is substantially higher than the total content of various metal ion impurities, preferably to a concentration of 10-13 g/l of Cu; blowing a hydrogen sulfide gas into the pretreated solution at a temperature of 40.degree. C. or higher until the redox potential of solution becomes a certain predetermined value to precipitate metal ions; filtering the treated solution to separate the residue available as a raw material for copper smelting from a filtrate which consists essentially of sulfuric acid; and returning the filtrate to the cell for electrolytic refining of copper.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.