Patent · US Expired

Chiral boron enolate reagents

US4405802A · kind A · utility

0Cited by
4References
8Claims
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Assignee

Inventors

Key dates

Filing dateFeb 22, 1982
Grant dateSep 20, 1983
Priority date
Expiry dateFeb 22, 2002

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC07F7/1804
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

Chiral boron enolates are provided having the formulae: ##STR1## wherein R.sub.2 B is 9-borobicyclo[3.3.1]non-9-yl(BBN) or R is n-butyl, cyclopentyl, or another alkyl group. The boron enolates can be condensed with aldehydes to produce aldol stereospecific product which includes a .beta.-hydroxy-.alpha.-methyl carbonyl unit in the product structure.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.