Patent · US Expired

Production of epoxy compounds from olefinic compounds

US4410714A · kind A · utility

31Cited by
4References
7Claims
0Family size

Assignee

Inventor

Key dates

Filing dateMay 3, 1979
Grant dateOct 18, 1983
Priority date
Expiry dateMay 3, 1999

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC07D301/26
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

A process for producing an epoxy compound by chlorinating a tertiary alkanol to the corresponding hypochlorite, followed by reaction of the hypochlorite with water and an olefinically unsaturated compound to produce the corresponding chlorohydrin and saponification of the chlorohydrin to the corresponding epoxy compound. The hypochlorite production and the saponification are effected with calcium oxide in an aqueous solution of calcium chloride, with calcium chloride being produced as by-product in an aqueous solution having a calcium chloride concentration of at least 25 wt. %. In this manner, calcium chloride by-product is recovered in a more usable form thereby eliminating the problems associated with recovery of calcium chloride by-product.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.