Patent · US Expired

Thermosetting aqueous coating compositions containing epoxy-phosphate dispersions

US4461857A · kind A · utility

45Cited by
4References
9Claims
0Family size

Assignee

Inventors

Key dates

Filing dateOct 31, 1983
Grant dateJul 24, 1984
Priority date
Expiry dateOct 31, 2003

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC09D163/00
  • WIPO fieldMacromolecular chemistry, polymers
  • WIPO sectorChemistry

Abstract

Aqueous thermosetting coating compositions are disclosed characterized by reduced curing requirements and which produce coatings having superior cured properties. These coatings comprise water containing water miscible organic solvent and the compositions have dispersed therein, based on total resin solids, from 25% to 85% of carboxy-functional organic solvent-soluble copolymer salt with a volatile amine in which the copolymer contains hydroxy groups providing an hydroxyl value in the range of 30 to 300, from 5% to 40% of a water soluble or water dispersible aminoplast or phenoplast curing agent, and from 2% to 35%, of a water dispersible epoxy phosphate ester polymer which is an oxirane-function-free, salt reaction product of (1) a monoester reaction product containing residual epoxy functionality, of (a) a resinous polyepoxide having at least about 1.4 oxirane groups per molecule, and (b) less than 0.9 mole of orthophosphoric acid for each oxirane equivalent in the polyepoxide, with (2) at least 1 mole of a volatile amine per equivalent of oxirane functionality in the monoester.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.