Patent · US Expired

Polymeric thickeners and coatings containing same

US4464524A · kind A · utility

40Cited by
5References
35Claims
0Family size

Assignee

Inventor

Key dates

Filing dateJul 26, 1983
Grant dateAug 7, 1984
Priority date
Expiry dateJul 26, 2003

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC08L33/10
  • WIPO fieldMacromolecular chemistry, polymers
  • WIPO sectorChemistry

Abstract

This invention relates to a latex thickener which consists essentially of the free radical addition product obtained by the emulsion polymerization of: PA1 (a) 3-15 parts styrene; PA1 (b) 15-45 parts ethyl acrylate; PA1 (c) 30-60 parts of at least one acid having the formula: ##STR1## wherein R.sub.1 and R.sub.2 can be the same or different and are hydrogen or lower alkyl of 1 to about 3 carbons; and PA1 (d) 10-25 parts of a mixture of esters; wherein the mixture of esters is the condensation reaction product of reactive amounts of (i) an ethylenically unsaturated cyclic carboxylic acid anhydride containing from 4 to about 8 carbon atoms; and (ii) an ethoxylated alcohol having the general formula: ##STR2## wherein R is from one to three aliphatic radicals of 1 to about 30 carbon atoms each and n is an integer from about 6 to 150; and (iii) a diol containing from about 2 to about 10 carbon atoms. The novel thickeners of this invention are especially useful in increasing the high shear viscosity of latex coating compositions, and especially coating compositions which contain polymeric vesiculated beads as part of the pigmentation.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.