Preparation of carbamates
US4474978A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Oct 17, 1983 |
| Grant date | Oct 2, 1984 |
| Priority date | — |
| Expiry date | Oct 17, 2003 |
Classification
- Technology area (CPC B)Performing Operations; Transporting
- CPC primaryB01J2531/824
- WIPO fieldChemical engineering
- WIPO sectorChemistry
Abstract
Process for the preparation of carbamates and/or derivatives thereof by reacting an organic compound containing at least one hydroxyl group with carbon monoxide and an organic nitrogeneous compound in the presence of a catalytic system based on palladium and a ligand according to the general formula: ##STR1## wherein L=N, P, As or Sb; R, R.sup.1, R.sup.2 and R.sup.3 are (un)substituted alkyl, aryl, alkaryl or aralkyl or R and R.sup.1 and/or R.sup.2 and R.sup.3 may form a ring together with the atom L to which they are attached; R.sup.4 and R.sup.5 are H or lower alkyl and n=2, 3 or 4, whereas carbon atoms between the groups L may be part of cyclic or non-cyclic unsaturated structures, and in the presence of an acid promoter.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.