Patent · US Expired

Separation of isotopes of zirconium

US4490225A · kind A · utility

4Cited by
10References
2Claims
0Family size

Assignee

Inventors

Key dates

Filing dateSep 7, 1982
Grant dateDec 25, 1984
Priority date
Expiry dateSep 7, 2002

Classification

  • Technology area (CPC B)Performing Operations; Transporting
  • CPC primaryB01D59/34
  • WIPO fieldChemical engineering
  • WIPO sectorChemistry

Abstract

Vapor of dicyclopentadienyl zirconium dicyanate is irradiated by a laser beam of a CO.sub.2 laser tuned to the stretching frequency of the .sup.S Zr-O-C bond of the dicyanate where .sup.S Zr is a selected isotope of zirconium. The excited component of the irradiated dicyanate including the .sup.S Zr is decomposed and is separated from the remainder. The dicyanate is readily prepared in large quantities, resists hydrolysis, sublimes at a temperature well below its dissociation temperature, and has a lower molecular weight than other proposed compounds such as dicyclopentadienyl zirconium diisopropoxide, and dicyclopentadienyl zirconium-di-tert-butoxide

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.