Patent · US Expired

Leached catalyst for ammonia synthesis

US4499204A · kind A · utility

10Cited by
3References
14Claims
0Family size

Assignee

Inventors

Key dates

Filing dateJan 3, 1984
Grant dateFeb 12, 1985
Priority date
Expiry dateJan 3, 2004

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY02P20/52
  • WIPO fieldMaterials, metallurgy
  • WIPO sectorChemistry

Abstract

An improved catalyst for the synthesis of ammonia is described wherein a promoted iron-derived, pre-reduced catalyst is oxidatively leached with a neutral aqueous solution of potassium cyanide. Preferably an organic carboxylic acid such as citric acid is added to the aqueous solution to maintain the pH at about neutral. The resulting leached catalyst has a markedly higher activity than the unleached catalyst. The leached catalyst may be contacted with a cobalt complex or a nickel salt to incorporate cobalt or nickel therein which catalysts are also useful for ammonia synthesis.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.