Patent · US Expired

ABS Compositions and process for preparing same

US4510287A · kind A · utility

16Cited by
7References
4Claims
0Family size

Assignee

Inventor

Key dates

Filing dateNov 21, 1983
Grant dateApr 9, 1985
Priority date
Expiry dateNov 21, 2003

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC08F279/04
  • WIPO fieldMacromolecular chemistry, polymers
  • WIPO sectorChemistry

Abstract

An intermediate for use in a polyblend consisting essentially of a copolymer of monoalkenyl aromatic monomer such as styrene and a ethylenically unsaturated nitrile monomer such as acrylonitrile surface grafted onto rubber which is dispersed in a matrix copolymer of the graft copolymer monomers, the dispersed phase being monomodal in particle size distribution and the weight percent of surface-grafted nitrile monomer being less by at least 2% than the weight percent nitrile monomer in the matrix. This intermediate with mismatched nitrile monomer can be blended with another rubber graft copolymer of different particle size dispersed in ungrafted matrix which contains matched nitrile monomer in the surface graft and matrix to provide a polyblend having properties at least equivalent to those obtained by blending two rubber graft copolymers of different particle size dispersed in a matrix which each contain matched nitrile monomer levels in the surface graft and matrix. The mismatched intermediate is prepared by continuous mass polymerization.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.