Patent · US Expired

Polymerization process

US4517345A · kind A · utility

15Cited by
9References
10Claims
0Family size

Assignee

Inventors

Key dates

Filing dateAug 23, 1982
Grant dateMay 14, 1985
Priority date
Expiry dateAug 23, 2002

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY10S526/903
  • WIPO fieldMacromolecular chemistry, polymers
  • WIPO sectorChemistry

Abstract

A process and catalyst for polymerizing olefins, especially ethylene or a mixture of ethylene with up to 40 wt % (based on total monomer) or other 1-olefinic monomer, the process comprising (a) supporting a chromium compound on a refractory oxide support material, (b) adding one or more tetravalent titanium compounds, (c) heating the product under such conditions that an active polymerization catalyst in the presence of one or more organometallic compounds wherein the metal is of groups 1A, 2A, 2B or 3A of the Periodic Table (Mendeleef), especially aluminium trialkyls. Step (d) is preferably carried out in the presence of a polyene modifier. The refractory oxide support material is preferably silica. The produced polyolefins are also claimed.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.