Patent · US Expired

Vinyl acetate/ethylene copolymer emulsions exhibiting both partially- and fully-hydrolyzed polyvinyl alcohol compatibility

US4521561A · kind A · utility

28Cited by
7References
13Claims
0Family size

Assignee

Inventors

Key dates

Filing dateFeb 29, 1984
Grant dateJun 4, 1985
Priority date
Expiry dateFeb 29, 2004

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC08L2666/04
  • WIPO fieldMacromolecular chemistry, polymers
  • WIPO sectorChemistry

Abstract

A vinyl acetate/ethylene copolymer emulsion exhibiting both partially- and fully-hydrolyzed polyvinyl alcohol compatibility which comprises an aqueous colloidal dispersion of a copolymer prepared by the emulsion polymerization of vinyl acetate and ethylene in the presence of a polyvinyl alcohol stabilizing system having an 8 to 10 mole % residual vinyl acetate content, especially comprising a mixture of a polyvinyl alcohol having a 3 to 6 mole % vinyl acetate content and a polyvinyl alcohol having a 10 to 14 mole % vinyl acetate content in a ratio that yields an average residual vinyl acetate content of 8 to 10 mole %. When blended with a partially- or fully-hydrolyzed polyvinyl alcohol to provided an adhesive composition, such compositions demonstrate an enhanced plasticizer thickening.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.