Patent · US Expired

Process for concurrent steam generation and metal recovery

US4524049A · kind A · utility

16Cited by
10References
18Claims
0Family size

Assignee

Inventor

Key dates

Filing dateAug 31, 1983
Grant dateJun 18, 1985
Priority date
Expiry dateAug 31, 2003

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC22B34/22
  • WIPO fieldMaterials, metallurgy
  • WIPO sectorChemistry

Abstract

Vanadium and nickel are recovered from fluid coke or fly ash concurrently with cogeneration of steam by a wet oxidation process at 500.degree.-650.degree. F. and elevated pressure, with a leaching pH of approximately 0.3 maintained by generation of sulfuric acid in situ. Vanadium products are precipitated by oxidation with for example sodium perchlorate with concurrent or subsequent pH adjustment to about pH 2. Following separation of the vanadium pentoxide, nickel powder is preferentially recovered by reduction with hydrogen and ammonia. Steam is generated by recovery of the thermal energy present in the offgases.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.