Patent · US Expired

Preparation of .alpha.-monoolefin homopolymers and copolymers

US4526944A · kind A · utility

4Cited by
2References
2Claims
0Family size

Assignee

Inventor

Key dates

Filing dateMar 3, 1981
Grant dateJul 2, 1985
Priority date
Expiry dateMar 3, 2001

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY10S526/906
  • WIPO fieldMacromolecular chemistry, polymers
  • WIPO sectorChemistry

Abstract

A process for the preparation of homopolymers and copolymers of .alpha.-monoolefins by means of a Ziegler-Natta catalyst system comprising (1) a halide of trivalent titanium, (2) an oxygen compound (ester) having a specific formula and (3) an aluminum-alkyl, the titanium halide (1) and the oxygen compound (2) being milled together before use, wherein the catalyst system employed contains, as a further component, (4) a phenolic compound of the formula ##STR1## where R.sup.3 is C.sub.1 -C.sub.6 -alkyl, R.sup.4 is hydrogen or C.sub.1 -C.sub.6 -alkyl, p is an integer from 0 to 5 and q is an integer from 1 to 5.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.