Patent · US Expired

Photographic products and processes with color shifted dye

US4535051A · kind A · utility

8Cited by
8References
21Claims
0Family size

Assignee

Inventors

Key dates

Filing dateAug 27, 1984
Grant dateAug 13, 1985
Priority date
Expiry dateAug 27, 2004

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY10S430/159
  • WIPO fieldBasic materials chemistry
  • WIPO sectorChemistry

Abstract

Photographic products and processes for the imagewise generation of a dye from a color shifted dye precursor of a preformed image dye, said precursor having at least one ##STR1## group, wherein R is hydrogen, alkyl, provided that the .alpha.- carbon does not have a hydrogen atom attached thereto, aryl such as phenyl or substituted phenyl, e.g. p-nitrophenyl, or heterocyclic such as pyridine; R.sub.1 -R.sub.6 are hydrogen, alkyl, preferably having from 1 to 6 carbon atoms, or aryl; n is 0 or 1; and T is a moiety containing a thiazolidin-2-yl group which upon silver-assisted cleavage of said thiazolidin-2-yl group results in the formation of a ##STR2## group, which may be protonated under the reaction conditions, followed by cleavage of said ##STR3## which cleavage is anchimerically assisted or accelerated by said ##STR4## to provide after protonation, an ##STR5## group in a dye chromophore. In a preferred embodiment the precursor is a substantially colorless compound.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.