Patent · US Expired

Catalyst component for .alpha.-olefin polymerization

US4535069A · kind A · utility

5Cited by
6References
13Claims
0Family size

Assignee

Inventors

Key dates

Filing dateFeb 16, 1983
Grant dateAug 13, 1985
Priority date
Expiry dateFeb 16, 2003

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC08F10/00
  • WIPO fieldMacromolecular chemistry, polymers
  • WIPO sectorChemistry

Abstract

A supported type catalyst component for .alpha.-olefin polymerization, having a higher activity and capable of affording a highly stereoregular polymer is provided, which component comprises a solid product (II) obtained by reacting Mg compound(s) of formula MgR.sup.1 R.sup.2 (wherein R.sup.1 is alkyl, aryl, alkoxy or aryloxy and R.sup.2, alkyl, aryl, alkoxy, aryloxy or halogen), with a complex of compound(s) selected from Al halides and Al compounds of formula AlR.sub.n.sup.3 X.sub.3-n (wherein R.sub.3 is alkyl, aryl, alkoxy or aryloxy; X, halogen; 0.ltoreq.n<2) with an organic acid ester; and reacting the resulting solid product (I) (a carrier) with a liquid halogen-containing Ti compound. Preactivation of the solid product (II) with an organoaluminum compound and an .alpha.-olefin affords a catalyst component superior in storage stability and polymerization reproducibility.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.