Patent · US Expired

Preparation of carbamates

US4550188A · kind A · utility

14Cited by
6References
19Claims
0Family size

Assignee

Inventors

Key dates

Filing dateJun 27, 1984
Grant dateOct 29, 1985
Priority date
Expiry dateJun 27, 2004

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC07C271/06
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

Disclosed is an improved process for the preparation of carbamates by heating an organic carbonate and an aromatic amine in the presence of aluminum as catalyst and a promoter comprising a combination of iodine and a mercury salt. High reaction temperatures are avoided by the process and conversions to carbamate products are high. Additionally, the process is economically attractive because even the common aluminum foil can be used as the catalyst. The products prepared by the process can be used in the production of insecticides, and, particularly, as intermediates in the preparation of organic mono- and polyisocyanates.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.